Practice Thermodynamics MCQs for Pharm-D Entry Test (D Pharmacy) Physics — topic-wise sets with solved answers.
Q1. A gas expands isothermally. What happens to its internal energy?
Answer: Remains constant
Explanation: Internal energy remains constant in isothermal expansion for ideal gases. Other options are incorrect as they imply energy change.
Q2. What is the SI unit of entropy?
Answer: J/K
Explanation: Entropy is measured in J/K. Other options are units for different physical quantities, not entropy.
Q3. A heat engine operates between 500K and 300K. What is its maximum efficiency?
Answer: 40%
Explanation: Maximum efficiency = 1 - (T_cold/T_hot) = 1 - (300/500) = 0.4 or 40%. Other options are incorrect calculations.
Q4. What is the process called when a system absorbs heat without a change in temperature?
Answer: Isothermal
Explanation: Isothermal process occurs at constant temperature. Other options describe different thermodynamic processes.
Q5. For an ideal gas, which of the following is true during an adiabatic expansion?
Answer: Temperature decreases
Explanation: In adiabatic expansion, temperature decreases as work is done at the expense of internal energy. Other options are incorrect.
Q6. The zeroth law of thermodynamics is related to which concept?
Answer: Temperature
Explanation: Zeroth law of thermodynamics defines temperature. Other options are related to different thermodynamic concepts.
Q7. A refrigerator works on the principle of
Answer: Reversed Carnot cycle
Explanation: Refrigerator works on reversed Carnot cycle, transferring heat from cold to hot. Other options are related but not the principle.
Q8. The change in internal energy of a system is given by
Answer: ΔU = Q + W
Explanation: First law of thermodynamics states ΔU = Q + W, where W is work done on the system. Other options are incorrect sign conventions.
Q9. For a given isothermal process, the work done is maximum when
Answer: The process is reversible
Explanation: Maximum work is done in a reversible isothermal expansion. Other options do not maximize work done.
Q10. The coefficient of performance (COP) of a refrigerator is given by
Answer: T_cold / (T_hot - T_cold)
Explanation: COP = T_cold / (T_hot - T_cold) for a refrigerator. Other options are incorrect or related to different quantities.
Q11. What happens to the entropy of the universe in a spontaneous process?
Answer: Increases
Explanation: Entropy of the universe always increases in a spontaneous process. Other options are incorrect as they violate the second law.
Q12. The internal energy of an ideal gas depends on
Answer: Temperature only
Explanation: For an ideal gas, internal energy is a function of temperature only. Other options are incorrect as they imply additional dependencies.
Q13. A thermodynamic process occurs at constant volume. What is it called?
Answer: Isochoric
Explanation: Isochoric process occurs at constant volume. Other options describe different thermodynamic processes.
Q14. The efficiency of a Carnot engine is 0.5. What is the temperature of the cold reservoir if the hot reservoir is at 500K?
Answer: 250K
Explanation: Efficiency = 1 - (T_cold/T_hot). Given efficiency = 0.5 and T_hot = 500K, T_cold = 250K. Other options are incorrect temperatures.
Q15. In a cyclic process, the change in internal energy is
Answer: Zero
Explanation: In a cyclic process, the system returns to its initial state, so ΔU = 0. Other options imply a change in state.
Q16. What is the condition for a process to be reversible?
Answer: It must be quasi-static
Explanation: A reversible process must be quasi-static and have no dissipative forces. Other options describe specific types of processes, not the condition for reversibility.
Q17. The second law of thermodynamics implies that
Answer: The total entropy of an isolated system can never decrease
Explanation: The second law states that total entropy of an isolated system always increases or remains constant. Other options violate the second law.
Q18. For an ideal gas, the molar specific heat at constant pressure is
Answer: Greater than at constant volume
Explanation: C_p > C_v because at constant pressure, the gas does work in addition to the energy required to raise the temperature. Other options are incorrect comparisons.
Q19. In an adiabatic process, the heat transfer (Q) is
Answer: Zero
Explanation: In an adiabatic process, Q = 0 by definition. Other options are incorrect as they imply heat transfer.
Q20. A thermodynamic system's internal energy increases by 100 J when 200 J of heat is added and it does 100 J of work. Is this possible?
Answer: No, never
Explanation: ΔU = Q + W = 200 J - 100 J = 100 J, which matches the given increase in internal energy, so it's possible but not related to being isobaric or adiabatic. The statement is actually true according to the first law.
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