MDCAT Chemistry MCQ #5412

When phosphorus pentachloride is treated with a limited amount of water, it undergoes partial hydrolysis. What is the primary phosphorus-containing product formed in this initial stage?

MDCAT Chemistry MCQ #5412

  1. Question 1

    Q1. When phosphorus pentachloride is treated with a limited amount of water, it undergoes partial hydrolysis. What is the primary phosphorus-containing product formed in this initial stage?

    • A) Phosphorus oxychloride (POCl3)
    • B) Phosphorous acid (H3PO3)
    • C) Phosphoric acid (H3PO4)
    • D) Phosphine gas (PH3)

    Answer: Phosphorus oxychloride (POCl3)

    Explanation: PCl5 reacts with limited water to form POCl3 and HCl; full hydrolysis to H3PO4 only occurs with excess water.